Abstract
AbstractStereospecific polymerization of conjugated dienes, especially 1,3‐butadiene and isoprene, is summarized. Various transition metal catalysts are utilized for the stereospecific polymerization of conjugated dienes. For example, Ti, V, Co, Ni, and lanthanides forcis‐1,4‐polymerization of 1,3‐butadiene, V, Cr, Fe, and lanthanides fortrans‐1,4‐polymerization of 1,3‐butadiene, and Cr, Co, and Fe for 1,2‐polymerization of 1,3‐butadiene. Lanthanide catalysts are very effective for stereospecific polymerization of isoprene. Stereospecific living polymerization of conjugated dienes is also achieved. A mechanism of the polymerization affording stereoregular polymers and stereospecific polymerization of other diene monomers is also mentioned.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
