Abstract
AbstractThe behavior of readily available enantiopure cis and trans 3,6‐disubstituted dihydropyran‐3‐ols and derivatives in epoxidation, osmium‐catalyzed dihydroxylations, SN2′, and Claisen‐related processes has been examined. The highly diastereoselective dihydroxylation of a suitably functionalized cis 3,6‐disubstituted dihydropyran‐3‐ol has been used in the synthesis of ethyl deoxymonate B from a 3‐sulfinyldihydropyran intermediate. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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