Abstract
Methylation of t-butyl-1-dimethylphosphono-2-p-tolylsulfinyl cyclopropanecarboxylic ester occurs with full inversion of the configuration, but the stereochemistry of carbanion formation is structure-dependent. Reaction of cyclopropyl sulfoxide with i-PrMgCl leads to unprecedented 1,2 migration of the phosphoryl group.
Published Version
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