Abstract
AbstractHydrometallation reactions, for example, hydroboration and hydroalumination, on [1‐(trifluoromethyl)propargyl]amines lead stereoselectively to the corresponding [(Z)‐ and (E)‐1‐(trifluoromethyl)allyl]amines in good yields; (Z)‐ and (E)‐allylamines with a free amino group can be obtained in good yields and excellent enantioselectivities from the chiral propargylamines.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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