Abstract
The alkynyl [Rh(C≡C-Ph)(nbd){Ph2P(CH2)3Z}2] and [Rh(C≡C-Ph)(cod){Ph2P(CH2)3Z}] (cod = 1,5-cycloctadiene, nbd = 2,5-norbornadiene) and methyl complexes [Rh(CH3)(cod){Ph2P(CH2)3Z}] featuring functionalized phosphine ligands (Z = NMe2, OEt) have been prepared. These complexes efficiently catalyze...
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