Abstract
A new type of stereoregular hybrid azobenzene-organocyclosiloxane discrete molecular structures with photoactive azobenzene groups unidirectionally connected to rigid cyclosiloxane frames through alkyl spacers of different lengths were developed for the first time.The kinetics and thermodynamics of nondegradative reversible trans-cis photoisomerization processes of the synthesized azobenzene-cyclosiloxane conjugates investigated using UV/Vis spectroscopy, DSC and XRD methods showed dependency on their molecular structures.It has been observed that room temperature UV (365 nm) irradiation of the synthesized hybrids leads to photoliquefaction effect consisting of a photoinduced phase transition of crystal solids into liquids. The photoliquefaction process was observed and confirmed with DSC, XRD and POM methods. Backward solidification process was generated with visible light and by heating.The tetra-azobenzene substituted cyclosiloxane single molecule compounds described in this work can be regarded as promising candidates for the development of new hybrid smart materials with many potential high-tech applications.
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