Stereometric and fractal analysis of granulated silver films used in thin-film hybrid structures.

Abstract

Silver nanostructures are of interest to be used in hybrid thin-film structures with various materials. In this work, we analyse 3D AFM images of granulated silver film nanostructures prepared by thermal evaporation. The advanced AFM data study aims to understand how film thickness and postannealing affect the nanostructure morphology changes. For the first time, the evaluation of surface statistical parameters and fractal geometry were used to characterise the nanostructure morphology of Ag island films. The samples with gravimetric thickness of 2, 4 and 10 nm were analysed before and after annealing at 200°C for 10 min. The statistical processing revealed the essential variation of parameters with Ag film thickness increment and as a postannealing result. The nonmonotonic variation of surface roughness, skewness and fractal dimensions were found. It is caused by the features of the film growth process with the thickness increment and thermally activated diffusion of Ag nanoparticles during annealing. LAY DESCRIPTION: Silver nanostructures are of great scientific interest due to their unique properties and wide applicability. In this work, we analyse microscopic 3D images of silver nanostructures deposited on quartz in vacuum chamber. Such thin-film nanostructures consisted of silver nanoparticles attached to the surface of quartz substrate. We aimed at studying how effective film thickness and postannealing affect the nanostructure shapes and forms. Effective thickness is the equivalent thickness of a smooth film. For this purposes we used special parameters called statistical parameters and fractal geometry to investigate nanostructures. The samples with effective thickness of 2, 4 and 10 nm were analysed before and after annealing at 200°C for 10 min. It has been shown, that effective Ag film thickness and postannealing results in variation of nanostructures forms. We have shown that the variation of statistical parameters were nonmonotonic. It is caused by the features of the film growth process with the thickness increment and thermally activated diffusion of Ag nanoparticles during annealing.