Abstract
Hydrosilylation of 1-alkynes catalyzed by RhI(PPh 3) 3 gives ( E)- and ( Z)-alkenylsilanes in a stereodivergent manner by switching the reaction conditions and the order of the addition of the reagents. The reaction is also applied to the synthesis of silicon-containing polymers with ( E) and ( Z) main-chain structures via polyaddition.
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