Abstract

Precipitates from acetonitrile solutions of poly(D-lactic acid) (PDLA)+poly(L-lactic acid) (PLLA) mixtures obtained under various conditions by changing the mixing ratio of the isomers, the polymer concentrations, the molecular weights of the polymers, and the solution temperature were found to contain only racemic crystallites (stereocomplexes) consisting of equimolar amounts of D-monomer and L-monomer units, independent of the PDLA content in the initial acetonitrile solution

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