Abstract

Contents Chapter 1.General Introduction A.General Introduction / p1 B.References / p12 Chapter 2.Syntheses and Characterization of Intra- and Intermolecular Hydrogen Bonding Isomers of P-H(Apical) Phosphoranes Bearing a Hydroxy Group. A.Introduction / p16 B.Results and Discussion / p18 C.Experimental Section / p38 D.References / p55 Chapter 3.First Characterization of 10-P-5 Spirophosphoranes with an Apical Carbon-Equatorial Oxygen ring. Kinetic Studies on Pseudorotation. A.Introduction / p57 B.Results and Discussion / p60 C.Experimental Section / p75 D.References / p99 Chapter 4.Kinetic Studies of Thermal Cyclization Reactions of P-H(apical) Phosphoranes Bearing a Hydroxy Group. A.Introduction / p101 B.Results and Discussion / p104 C.Experimental Section / p115 D.References / p136 Acknowledgements / p138 List of Publications / p139

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