Abstract
The four α-hydroxybornanones have been obtained as their crystalline p-chlorobenzoates; the two endo ketoesters via photochemical reaction of camphorquinone and p-chlorobenzaldehyde and the two exo-isomers from cis, exo-bornanediol. cis-Diols were produced in every case by reaction of these ketoersters with p-methylbenzyl magnesium chloride, the endo-ketoesters affording cis, endo-diols via exo attack of the Grignard reagent on the bornane system. Two of the possible trans-diols were also synthesized.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.