Stereochemical Deuterium Labeling as Mechanistic Probe for Differentiating the Singlet- and Triplet-Diradical Spin States in the Rearrangement of the 2-Spiroepoxy-1,3-cyclopentanediyl to Oxetanes

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTStereochemical Deuterium Labeling as Mechanistic Probe for Differentiating the Singlet- and Triplet-Diradical Spin States in the Rearrangement of the 2-Spiroepoxy-1,3-cyclopentanediyl to OxetanesManabu Abe, Waldemar Adam, Yasunori Ino, and Masatomo NojimaView Author Information Department of Materials Chemistry, Graduate School of Engineering Osaka University, Suita 565-0871, Osaka, Japan Insitut für Organische Chemie der Universität Würzburg Am Hubland,D-97074 Würzburg, Germany Cite this: J. Am. Chem. Soc. 2000, 122, 27, 6508–6509Publication Date (Web):June 23, 2000Publication History Received23 February 2000Published online23 June 2000Published inissue 1 July 2000https://doi.org/10.1021/ja000656sCopyright © 2000 American Chemical SocietyRIGHTS & PERMISSIONSArticle Views195Altmetric-Citations7LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit Read OnlinePDF (46 KB) Get e-AlertsSupporting Info (1)»Supporting Information Supporting Information SUBJECTS:Chromophores,Hydrogen isotopes,Irradiation,Photodissociation,Quantum mechanics Get e-Alerts