Abstract
The stereochemistry of α1, the first identified mating hormone of the plant pathogen Phytophthora, has been unknown due to its acyclic flexible nature. Here, two stereogenic centers of α1 are determined to be (3 RS,15 R)-configuration by NMR analysis of the Mosher’s esters of α1 and a synthetic model compound. The information obtained here will be helpful for reducing the burden of the researchers who are trying to synthesize all the possible stereoisomers of α1 to elucidate its full stereochemistry.
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