Abstract
The E(0 g + ) ion-pair state of Cl 2 has been investigated by stepwise two-photon excitation through the B 3 Π(0 u + ) state. The method yields rovibronically resolved E-B emission spectra, which are analyzed as a function of excitation wavelength. The E(0 g + ) state is identified as lying at T e = 57820 cm −1 and is characterized by ω e = 250 cm −1 and r e = 2.89 A.
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