Abstract
The fluorination of [MeAlN(2,6- i-Pr 2C 6H 3)] 3 1 using 1 and 2 eq., respectively, trimethyltin fluoride leads to the mono- and difluoro compounds, [FAl(MeAl) 2(N(2,6- i-Pr 2C 6H 3)) 3]·2THF 2 and [(FAl) 2MeAl(N(2,6- i-Pr 2C 6H 3)) 3]·3THF 3, where each methyl group can be selectively exchanged for terminal fluorine atoms (AlF). The reaction of 1 and 3 eq. of trimethyltin fluoride leads to the trifluoro compound [FAlN(2,6- i-Pr 2C 6H 3)] 3·3THF 4 and [Me 2SnN(2,6- i-Pr 2C 6H 3)] 2 5 as a by-product. The core of compound 5 consists of a tin–nitrogen four-membered Sn 2N 2 ring.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callSimilar Papers
More From: Journal of Fluorine Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
