Steady-state fluorescence investigations of aqueous binary mixtures of myristyl alcohol based bis-sulfosuccinate anionic gemini surfactant and effect of different conventional surfactants therein

Abstract

ABSTRACTThe present research work is associated with the fluorescence investigations of binary aqueous mixed surfactants solutions of anionic bis-sulfosuccinate gemini surfactant (BSGSMA1,8) and three different conventional surfactants—anionic viz. sodium dodecyl sulfate (SDS), cationic viz. cetyl trimethyl ammonium bromide (CTAB), and nonionic surfactant viz. Triton X 100. Steady-state fluorescence spectroscopy technique has been utilized to examine the micellization behavior of aqueous solution of pure myristyl alcohol-based BSGSMA1,8 having flexible methylene chain [(CH2)8] as spacer group. Critical micelle concentration (CMC), aggregation number (N), and micropolarity of pure and mixed surfactants systems were explored during the investigations. The results revealed the best synergism behavior of prepared gemini BSGSMA1,8 with SDS as compared to CTAB and Triton X 100. The maximum reduction in the value of pyrene intensity ratio (I1/I3) was observed for gemini and SDS mixed surfactant solution. On the other hand, the increased I1/I3 value of mixed gemini with Triton X 100 exhibited that mixed surfactant system of anionic gemini BSGSMA1,8 with non-ionic Triton X 100 is not as compact as other mixed surfactant systems. Aggregation number increased and micropolarity decreased with increased concentration of gemini surfactants.