Staurolite-quartzite bands in kyanite quartzite at Big Rock, Rio Arriba County, New Mexico ? A discussion

Abstract

Schreyer and Chinner (1966) described staurolite-quartzite bands of unusual bulk chemical composition associated with the Big Rock kyanite deposit in northern New Mexico. They discussed two possible hypotheses-syngenetic or metasomatic-for the origin of the bands. This paper discusses additional evidence in support of the metasomatic hypothesis. Quartz-muscovite schist and quartz-kyanite rock are believed to be metarhyolite that was altered metasomatically by hydrothermal activity during metamorphism. Experimentally demonstrable reactions that involve ionic exchange equilibria between pore fluid and solid phases best explain the observed alteration. Staurolite-quartzite bands are postulated to be basalts or amphibolites that were hydrothermally altered in a manner analogous to alteration of the enclosing rocks. The process would deplete a basaltic parent rock in alkali and alkaline earth elements and produce a chemical composition similar to the bulk chemical composition of staurolite-quartzite. Schreyer and Chinner used textural evidence to prove that staurolite formed at the expense of chloritoid. Based on the chemical compositions of staurolite and relict chloritoid reported by them, several chemical equations were constructed, using the principle of ionic equilibria between pore fluid and solid phases, in an attempt to realistically portray the reaction. It is suggested that, under open-system metasomatic conditions, the ratio aMg+2/aH+ in the supercritical aqueous fluid is an important parameter that controls the stability of chloritoid vs. staurolite.