Statistical theory of rarified gases in the coulomb model of substance: Adiabatic approximation and initial atoms

Abstract

In the framework of the adiabatic approximation for a subsystem of nuclei with the average distance between them significantly exceeding the dimensions of the initial atom, we consider a nonrelativistic Coulomb system consisting of electrons and nuclei of one type for the temperature range where we can restrict ourself to using the ground state to describe the electron subsystem. We show that the equilibrium properties of such a system are equivalent to the thermodynamic properties of the one-component system of initial atoms interacting between themselves via a short-range potential that is the effective potential of the nucleus-nucleus interaction. In the framework of the applicability of Boltzmann statistics, we present quantum group expansions for the thermodynamic properties of a chemically reacting rarified gas that correspond to the method of initial atoms.