Abstract
Making use of the invariant property of the equilibrium size distribution of the hydrogen bonding clus-ters formed in hydrogen bonding system of A a D d type, the analytical expressions of the free energy in pregel and postgel regimes are obtained. Then the gel free energy and the scaling behavior of the number of hydrogen bonds in gel phase near the critical point are investigated to give the corre-sponding scaling exponents and scaling law. Meanwhile, some properties of intermolecular and in-tramolecular hydrogen bonds in the system, sol and gel phases are discussed. As a result, the explicit relationship between the number of intramolecular hydrogen bonds and hydrogen bonding degree is obtained.
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