Abstract
ABSTRACT The occurrence of coal spontaneous combustion has a significant impact on both the safety of personnel and mine recovery. In order to establish an early warning system for combustion, it is crucial to develop a mathematical model that characterizes indicator gases and coal temperature. In this study, we investigated the O2, CO, and CO2 characteristics of data collected from a goaf beam pipe in the Mengcun mine. Our findings demonstrate a linear decrease in O2 concentration with goaf depth and a strong negative correlation between CO and O2. We observed that CO/∆O2 and CO/CO2 increased to a maximum and then decreased as the goaf depth increased. Furthermore, we found that the peaks of these parameters at the same sampling point corresponded to the same goaf depth, and both occurred at the junction between the air-leakage and oxidation zones. By using a logistic model to fit the CO and C2H4 data, we developed a model that characterizes the relationships among CO, C2H4, and coal temperature based on statistical laws. The model provides direct information about the inflection point temperatures of C2H4 and CO, with the former being slightly lower within the same coal sample. The overall difference between the inflection point temperatures is relatively small, about 10°C. The initial temperature ratio of C2H4 and CO remains essentially constant at 3.8. C2H2 concentrations are low and irregular, and the presence of this gas can be used to assess when coal enters the accelerated oxidation stage. This research result provides a new research view for elucidating the distribution characteristics of coal spontaneous combustion index gas.
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