Abstract

A statistical formulation is developed describing the composition in an evaporating multicomponent-fuel liquid drop and in the gas phase surrounding it. When a complementary discrete-component model is used, it is shown that, when drops are immersed in a carrier gas containing fuel vapor, condensation of species onto the drop results in the development of a minor peak in the liquid composition probability distribution function (PDF). This peak leads to a PDF shape that can be viewed as a combination of two gamma PDFs, which is determined by five parameters. A model is developed for calculating the parameters of the two combined gamma PDFs. Extensive tests of the model for both diesel and gasoline show that the PDF results replicate accurately the discrete model predictions. Most important, the mean and variance of the composition at the drop surface are in excellent agreement with the discrete model. Results from the model show that although the second peak is minor for the liquid PDF, its corresponding peak for the vapor distribution at the drop surface has a comparable magnitude to and sometimes exceeds that corresponding to the first peak. Four-parameter models are also exercised, and it is shown that they are unable to capture the physics of the problem.

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