Abstract

In recent years, geopolymer has been developed as an alternative to Portland cement (PC) because of the significant carbon dioxide emissions produced by the cement manufacturing industry. A wide range of source binder materials has been used to prepare geopolymers; however, fly ash (FA) is the most used binder material for creating geopolymer concrete due to its low cost, wide availability, and increased potential for geopolymer preparation. In this paper, 247 experimental datasets were obtained from the literature to develop multiscale models to predict fly-ash-based geopolymer mortar compressive strength (CS). In the modeling process, thirteen different input model parameters were considered to estimate the CS of fly-ash-based geopolymer mortar. The collected data contained various mix proportions and different curing ages (1 to 28 days), as well as different curing temperatures. The CS of all types of cementitious composites, including geopolymer mortars, is one of the most important properties; thus, developing a credible model for forecasting CS has become a priority. Therefore, in this study, three different models, namely, linear regression (LR), multinominal logistic regression (MLR), and nonlinear regression (NLR) were developed to predict the CS of geopolymer mortar. The proposed models were then evaluated using different statistical assessments, including the coefficient of determination (R2), root mean squared error (RMSE), scatter index (SI), objective function value (OBJ), and mean absolute error (MAE). It was found that the NLR model performed better than the LR and MLR models. For the NLR model, R2, RMSE, SI, and OBJ were 0.933, 4.294 MPa, 0.138, 4.209, respectively. The SI value of NLR was 44 and 41% lower than the LR and MLR models’ SI values, respectively. From the sensitivity analysis result, the most effective parameters for predicting CS of geopolymer mortar were the SiO2 percentage of the FA and the alkaline liquid-to-binder ratio of the mixture.

Highlights

  • To meet the demands of the construction industry, Portland cement production has increased significantly in recent years

  • To develop reliable models for predicting the compressive strength of geopolymer mortar, a total of 247 datasets were collected from various research articles with varying mix proportions; after statistically analyzing the data and proposing models for CS prediction, the following conclusions were drawn: 1

  • Class F fly ash can be used as an aluminosilicate source material to synthesize geopolymer mortar with a strength as high as 80 MPa at 28 days

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Summary

Introduction

To meet the demands of the construction industry, Portland cement production has increased significantly in recent years. The effects of fly ash characteristics and alkaline activator components on the CS of fly-ash-based geopolymer mortar were investigated by Hadi et al [27] They prepared different geopolymer mortar mixtures, an artificial neural network was successfully designed to develop models to forecast the CS of their mortar specimens. They used nine input parameters in their model, including fly ash and alkaline activator properties; some other important parameters, such as the molarity of NaOH, sand content, curing temperature, curing time, and age of the samples were absent from their input model parameters. Exploration of the most influential parameters of FA-based geopolymer mortar for compressive strength

Methodology
Characteristics of Model Input Parameters
Fly Ash Content (FA)
Al2O3 (FAO)
Variation
Sand Content (S)
NaOH Content (SH)
SiO2/Na2O of Silicate Solution (SO/N)
H2O/Na
Liquid-to-Binder Ratio (l/b)
2.2.10. NaOH Molarity (M)
2.2.11. Curing
2.2.12. Curing Time (t)
14. Relationship
Modeling
Linear Regression (LR) Model
Multinominal Logistic Regression (MLR) Model
Model Evaluation Criteria
The LR Model
The NLR Model
Evaluation of Developed Model
Sensitivity Analysis
Conclusions
Full Text
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