Abstract
Abstract A previously devised statistical model for solvation shifts of ionization energies of atomic ions is extended to Auger transition energies. The model expresses the ionization shift, the Auger energy shift and the sum of these shifts in terms of expectation values taken over radial and angular distribution functions for the solvent. Numerical evaluation is performed for some monovalent anions and cations and for Mg 2+ in aqueous solutions. Results from the model are compared with experimental data for absolute photoelectron and Auger shifts as well as for the individual contribution to salvation energies that can be assessed from a combined use of ESCA data for photoelectron and Auger energy shifts.
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