Abstract

A novel approach to the analysis of the transient data from CSTR is illustrated on the catalytic dehydration of methanol. The method allows to determine adsorbed amounts of reaction components under reaction conditions and it is applicable in cases where at least one reaction component is not (or slighty) adsorbed. Because new types of data can be obtained in this way a deeper discrimination between rival kinetic models is possible. The method permits also determination of total concentration of active sites on the catalyst surface. Comparison of transient data analysis with the steady-state results is presented.

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