Static Structure Factor and Viscoelastic Properties of Dendrimer Grafted Nanoparticles in Solution.

Abstract

The theory for the dynamics of multiscale branched polymeric structures is applied to understand the dendrimer-grafted nanoparticles in a dilute solution. The multiscale nature of dendrimer-grafted nanoparticles arises due to larger beads for the nanoparticles and the smaller beads for the polymeric structure connected through the harmonic springs. The multiscale generalized Gaussian structure approach allows us to study several viscoelastic properties: (i) storage and loss moduli and (ii) intrinsic viscosity. The influence of nanoparticles in the dendrimer structure is reflected in low and intermediate frequency regimes of the viscoelastic relaxation moduli. The increase in the size and the number fraction of nanoparticle shows an anomalous enhancement in the relaxation moduli. The increase in number fraction of nanoparticle in dendrimer-grafted nanoparticles decreases the transition frequency between solid- and liquid-like viscoelastic region. The intrinsic viscosity of dendrimer-grafted nanoparticles increases with increasing the size of nanoparticle. The inclusion of hydrodynamic interactions facilitates the dynamics of dendrimer-grafted nanoparticles. The Kratky plot of the static structure factor of all conformation of dendrimer-grafted nanoparticles is also analyzed as a function of number fraction and the size of the nanoparticles. At low wavenumbers, all conformations of dendrimer-grafted nanoparticles show a universal behavior. The compactness of dendrimer-grafted nanoparticles increases with the increase in number fraction and the size of the nanoparticles.