Abstract

This review presents the results of cutting-edge research on chemiresistive gas sensors in Korea with a focus on the research activities of the laboratories of Professors Sang Sub Kim and Hyoun Woo Kim. The advances in the synthesis techniques and various strategies to enhance the gas-sensing performances of metal-oxide-, sulfide-, and polymer-based nanomaterials are described. In particular, the gas-sensing characteristics of different types of sensors reported in recent years, including core–shell, self-heated, irradiated, flexible, Si-based, glass, and metal–organic framework sensors, have been reviewed. The most crucial achievements include the optimization of shell thickness in core–shell gas sensors, decrease in applied voltage in self-heated gas sensors to less than 5 V, optimization of irradiation dose to achieve the highest response to gases, and the design of selective and highly flexible gas sensors-based WS2 nanosheets. The underlying sensing mechanisms are discussed in detail. In summary, this review provides an overview of the chemiresistive gas-sensing research activities led by the corresponding authors of this manuscript.

Highlights

  • IntroductionAtmospheric pollution typically comprises particulate matter, ozone (O3), sulfur dioxide (SO2), nitrogen dioxide (NO2), and carbon monoxide (CO) [1]

  • Overview of the Oxide-Based Gas SensorsAtmospheric pollution typically comprises particulate matter, ozone (O3), sulfur dioxide (SO2), nitrogen dioxide (NO2), and carbon monoxide (CO) [1]

  • Metal–oxide semiconductor (MOS) gas sensors, whose operation is based on the change in the resistance upon exposure to target gases, have attracted significant attention owing to their low cost, low toxicity, simple fabrication route, robustness, high stability, fast response/recovery times, and sensitivity to detect a wide range of target gases [18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62,63]

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Summary

Introduction

Atmospheric pollution typically comprises particulate matter, ozone (O3), sulfur dioxide (SO2), nitrogen dioxide (NO2), and carbon monoxide (CO) [1]. Metal–oxide semiconductor (MOS) gas sensors, whose operation is based on the change in the resistance upon exposure to target gases, have attracted significant attention owing to their low cost, low toxicity, simple fabrication route, robustness, high stability, fast response/recovery times, and sensitivity to detect a wide range of target gases [18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62,63]. This review paper presents a lot of information about different gas sensors and their sensing mechanism

Gas Sensors Based on Morphology Engineering
Irradiated Gas Sensors
Glass Gas Sensors
Si-Based Gas Sensors
H6 CO NO2 CO H2S
H2 NO2 NO2 NO2
Findings
Conclusions
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