Abstract

Supercapacitors are energy storage devices with high power density, rapid charge/discharge rate, and excellent cycle stability. Carbon-based supercapacitors are increasingly attracting attention because of their large surface area and high porosity. Carbon-based materials research has been recently centered on biomass-based materials due to the rising need to maintain a sustainable environment. Cellulose and lignin constitute the major components of lignocellulose biomass. Since they are renewable, sustainable, and readily accessible, lignin and cellulose-based supercapacitors are economically viable and environmentally friendly. This review aims to systematically analyze published research findings on electrospun lignin, cellulose, and lignin/cellulose nanofibers for use as supercapacitor electrode materials. A rigorous scientific approach was employed to screen the eligibility of relevant articles to be included in this study. The research questions and the inclusion criteria were clearly defined. The included articles were used to draw up the research framework and develop coherent taxonomy of literature. Taxonomy of research literature generated from the included articles was classified into review papers, electrospun lignin, cellulose, and lignin/cellulose nanofibers for use as supercapacitor electrode materials. Furthermore, challenges, recommendations, and research directions for future studies were equally discussed extensively. Before this study, no review on electrospun lignin/cellulose nanofiber-based supercapacitors has been reported. Thus, this systematic review will provide a reference for other researchers interested in developing biomass-based supercapacitors as an alternative to conventional supercapacitors based on petroleum products.

Highlights

  • Human activities, security, and industrialization depend on energy production and this energy is mostly derived from fossil fuels [1]

  • While research into supercapacitors based on lignin/cellulose is currently at its early stage, it is blend [23]

  • The main objective of this systematic review is to highlight the state of the art research on electrospun lignin and cellulose nanofibers for application in supercapacitors and to provide directions of future research on the area

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Summary

Introduction

Security, and industrialization depend on energy production and this energy is mostly derived from fossil fuels [1]. Energy Council (www.worldenergy.org) has estimated that by 2050, the world would demand twice its present energy consumption. Flexible supercapacitors are among the most investigated energy storage devices due to their high-power density, rapid charge/discharge rate, excellent cycle stability, and robust nature. Electrospun carbonaceous materials are used as electrode materials, conducting additives, and supporting substrates in EDLCs due to their excellent electrical conductivity, large surface area, high porosity, mechanical flexibility, and chemical stability [6]. Due to its wide surface area and high porosity, carbon-based supercapacitors draw more and more interest. It is necessary to opt for greener carbon sources for the production of CNFs

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