Standard molar volumes and heat capacities of aqueous solutions of sodium trifluoromethanesulfonate at temperatures up to 573 K and pressures to 28 MPa

Abstract

Densities and heat capacities of aqueous solutions of sodium trifluoromethanesulfonate (sodium triflate) of concentrations from 0.025 to 0.3mol·kg−1 were measured with high temperature, high pressure custom-made instruments at temperatures up to 573K and at pressures up to 28MPa. Standard molar volumes and standard molar heat capacities were obtained via extrapolation of the apparent molar properties to infinite dilution. The results for volumetric properties are consistent with earlier literature data, but no previous measurements exist for heat capacities of sodium triflate at superambient conditions. The new data were used for calculating the standard molar volumes and heat capacities for the triflate anion and compared with the results for triflic acid that should be essentially identical within the expected error margins. At temperatures above 473K an effort was made to refine the processing of literature data for HCl(aq), taking into account its partial association, and subsequently to modify the value for Na+ ion calculated from the standard thermodynamic values of NaCl(aq) where its ion pairing was already considered. This approach yields reasonable agreement at high temperatures between the values for triflate ion calculated from its salt and those for triflic acid.