Abstract
Under pressure: characterization of the high-pressure phase of crystalline [Co2(CO)6(PPh3)2] has provided the first structural evidence for the transformation from a staggered to eclipsed arrangement of the equatorial carbonyl ligands in a dimeric transition-metal complex (see picture). A comparison with the same phenomenon observed at low temperature (though arrested in the very early stages) is presented. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z502241_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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