Staged co‐gasification characteristics of pyrolyzed semi‐coke and antibiotic filter residue under oxy‐fuel condition

Abstract

AbstractPyrolyzed semi‐coke (SC) is a by‐product of coal‐graded utilization, while the clean and efficient utilization of excess powdery pyrolyzed SC has given a huge challenge. The antibiotic filter residue (AFR) is a kind of biomass solid wastes, which also requires proper disposal or resource utilization. Utilizing the fuel complementary characteristics of pyrolyzed SC and AFR, oxy‐fuel gasification co‐processing can not only effectively realize the resource utilization of solid wastes but also achieve significant CO2 reduction boosting carbon neutrality. Here, the Aspen Plus software was used to simulate the staged oxy‐fuel co‐gasification characteristics of SC and AFR. The simulation results show that with the increase of the SC proportion in blends from 0% to 100%, the lower heating value is raised from 9.48 to 11.26 MJ·m−3, the gas yield is increased from 1.39 to 2.55 m3·kg−1, and the cold gas efficiency grows by 39.28%. The rise of oxygen volume percentage improves the lower heating value in the produced gas and volume fraction of H2, but the contents of CO and CO2, together with the gas yield and cold gas efficiency, show decreasing trends. Raising gasification temperature within a reasonable range is beneficial for enhancing the gasification performance and improving the syngas quality. The raised oxygen equivalent ratio increases the content of CO2 but leads to the decline of CO and H2. For sample AFR, as the oxygen equivalent ratio is varied from 0.6 to 0.8, the volume fraction of CO2 increases by 14.19%, while the contents of CO and H2 reduce by 5.34% and 8.77%, respectively. The present study offers effective support for the co‐disposal and resource utilization of powdery pyrolyzed SC and AFR.