Abstract
In the title complex, [Pd2(C10H12O4)2(C10H8N2)2](PF6)2·CH3CN, the PdII centers have a distorted cis-square-planar geometry defined by an O,O′-bidentate bisacetylacetonate dianion ligand and a chelating 2,2′-bipyridine ligand. The crystal structure is stabilized by electrostatic forces between the cations and anions, intermolecular π–π stacking interactions between pairs of 2,2′-bipyridine rings, and weak intermolecular hydrogen bonds involving hexafluorophosphate anions (C—H⋯F) and the solvent acetonitrile molecules (C—H⋯N).
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