Stable Water Isotopes across a Transect of the Southern Alps, New Zealand

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Abstract Stable water isotope concentrations were obtained from samples of stream water at 29 sites in a west–east transect across the Southern Alps of New Zealand, where westerly conditions dominate the precipitation regime. The samples were taken from small catchment streams during a time of extended recession as a means of collecting time and space averages of the source precipitation. The isotopic concentrations from sites at either end of the transect lead to a drying ratio estimate of 22%–34% for this region of the Southern Alps. The isotope concentrations increased from west to east, indicating that precipitation in the lee area originates from higher and/or colder condensation than on the windward side. The transect was divided into three regions according to the deuterium-excess (d excess) results. Increasing d-excess values on the windward side of the mountains were speculated to be a result of some unknown combination of reducing relative evapotranspiration, increasing recycling of water vapor, and increasing nonequilibrating condensation from high-intensity precipitation. Low d-excess values in the region immediately lee of the mountains were consistent with below-cloud evaporation associated with increased hydrometeor drift into the drier lee side. High d excess in the more distant lee side was attributed to a secondary source of moisture (from the east and south). The information gained has supported current concepts of the precipitation processes dominant in the region and has provided additional quantitative measurements with which to validate future precipitation modeling efforts.