Abstract

The phase diagram of the stable tetrahedron NaCl – KCl – PbCl2 – PbWO4 of the quaternary reciprocal system Na, K, Pb // Cl, WO4 was first studied using methods of differential thermal analysis. Its phase diagram was triangulated and stable triangulating internal sections of NaCl – PbWO4 – KCl.2PbCl2, NaCl – PbWO4–2KCl. PbCl2 and obtained tetrahedra NaCl – PbCl2 – PbWO4 – KCl.2PbCl2, NaCl – KCl – PbWP4, and NaCl – KCl – PbWP4. There are coordinates of three quadruple invariant points revealed.

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