Abstract
A simple synthetic method for preparing stable colloidal dispersions that form polymeric films containing fluorinated acrylates is presented. The simultaneous presence of the dual tail anionic fluorosurfactant phosphoric acid bis(tridecafluorooctyl) ester ammonium salt (FSP) and sodium dodecyl sulfate (SDS) surfactants facilitates a suitable environment for the aqueous polymerization of methyl methacrylate/n-butyl acrylate/heptadecafluorodecyl methacrylate (MMA/nBA/FMA) colloidal particles. Polyermerization is achieved by a low-sheer monomer-starved emulsion polymerization process in which the FSP/SDS surfactant mixture significantly reduces the surface tension of the aqueous phase, thus facilitating mobility and subsequent polymerization of FMA along with MMA and nBA momomers. Using this approach, it is possible to obtain stable nonspherical MMA/nBA/FMA colloidal dispersions containing up to a 8.5% (w/w) copolymer content of FMA. These studies illustrate that the incorporation of FMA into MMA/nBA particle morphologies facilitates surface phase separation during coalescence, resulting in F-containing film−air (F−A) interfaces. Thus, surface properties with a significant decrease in the kinetic coefficient of friction as well as high contact angles can be produced.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
