Abstract
A short Ga-N bond with double-bond character is displayed by the first monomeric imide of gallium, which was obtained by the reaction of [{HC(MeCDippN)2 }M:] (Dipp=2,6-iPr2 C6 H3 , M=Ga; see picture) with N3 -2,6-Trip2 C6 H3 (Trip=2,4,6-iPr3 C6 H2 ). The analogous aluminum (M=Al) compound is also readily available.
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