Stable, Monomeric Imides of Aluminum and Gallium: Synthesis and Characterization of [{HC(MeCDippN)2 }MN-2,6-Trip2 C6 H3 ] (M=Al or Ga; Dipp=2,6-iPr2 C6 H3 ; Trip=2,4,6-iPr3 C6 H2 ).

Ned J Hardman,Chunming Cui,Herbert W Roesky,William H Fink,Philip P Power

doi:10.1002/1521-3773(20010601)40:11<2172::aid-anie2172>3.0.co;2-y

Stable, Monomeric Imides of Aluminum and Gallium: Synthesis and Characterization of [{HC(MeCDippN)2 }MN-2,6-Trip2 C6 H3 ] (M=Al or Ga; Dipp=2,6-iPr2 C6 H3 ; Trip=2,4,6-iPr3 C6 H2 ).

Ned J Hardman, Chunming Cui + Show 3 more

https://doi.org/10.1002/1521-3773(20010601)40:11<2172::aid-anie2172>3.0.co;2-y

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Journal: Angewandte Chemie International Edition	Publication Date: May 28, 2001
Citations: 154

Affiliation: University of California, Davis, University of Göttingen

#C6 H3 #C6 H2 + Show 6 more

Abstract
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Abstract

A short Ga-N bond with double-bond character is displayed by the first monomeric imide of gallium, which was obtained by the reaction of [{HC(MeCDippN)2 }M:] (Dipp=2,6-iPr2 C6 H3 , M=Ga; see picture) with N3 -2,6-Trip2 C6 H3 (Trip=2,4,6-iPr3 C6 H2 ). The analogous aluminum (M=Al) compound is also readily available.

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