Abstract
The new mononuclear manganese(II) complex with chlorido-substituted hexadentate Schiff base (H23,5-2Cl-sal-N(1,5,8,12) = N,N′-Bis[3-(3,5-dichloridosalicylideneamino)propyl]-ethane-1,2-diamine) were synthesized and its crystal structure was solved using single-crystal X-ray diffraction. The complex crystallizes in a triclinic system with a P1¯ space group. Manganese(II) central atom is coordinated by two atoms of oxygen and four atoms of nitrogen of the Schiff base. The supramolecular structure of the complex and the intermolecular interactions were analyzed using Hirshfeld surface analysis. The complex was characterized by UV–vis and infrared spectra, and the presence of a high-spin Mn(II) state (S = 5/2) was revealed by EPR spectroscopy in the solid state.
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