Stable fouling resistance of polyethylene (PE) separator membrane via oxygen plasma plus zwitterion grafting

Abstract

Low-cost and fouling resistant microfiltration/ultrafiltration membranes for wastewater treatment has been a challenging task when balancing the membrane cost and performance stability. Herein, a low-cost polyethylene (PE) lithium-ion battery separator was explored as a potential solution. To tackle the intrinsic hydrophobic character which incurs severe fouling, a novel cascade process of plasma treatment plus zwitterion grafting was designed: first oxygen plasma to endow oxygen-containing groups for hydrophilicity and supply “grafting sites”, and grafting zwitterion 3-[[3-(trimethoxysilane)-propyl] amino] propane-1-sulfonic acid (TMAPS) for robust fouling resistance. The membranes were analyzed by water contact angle, Fourier-transform Infrared Spectroscopy (FTIR), Energy Dispersive Spectroscopy (EDS), and X-ray Photoelectron Spectroscopy (XPS). Challenged by two typical foulants, e.g., humic acid (HA) and bovine serum albumin (BSA), the zwitterion grafted membrane showed the best antifouling performance. Oxygen plasma treated PE membrane presented a better performance towards HA than to BSA. The Resistance-in-Series model revealed that the plasma-treated membrane showed improvement in reversible resistance but not in irreversible resistance. Migration of hydrophobic PE segment to the surface due to the low glass transition temperature was attributed to the low fouling resistance of the plasma-treated membrane. However, the zwitterion-grafted membrane led to stabilized hydrophilicity and inhibited the hdrophobic-hydrophobic interaction between the membrane and foulant, thus resulting to significantly improved flux recovery and low irreversible fouling rate. This study clarified that oxygen plasma alone is not sufficient to provide sufficient fouling resistance, but grafting with zwitterion provides stable hydrophilicity and fouling resistance.