Abstract
The first stable neutral formyl complexes of a light transition metal, the title compounds 2 with aryl phosphite ligands, were prepared by reduction of the cations of 1. Formyl complexes have been postulated as intermediates in the homogeneous catalytic hydrogenation of CO (L P(OPh)3, L′ CO; L P(o-OTolyl)3, L′ CO; L L′ P(OPh)3).
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