Abstract

To obtain high-quality n-type doped β-Ga2O3 films, silane was used as an n-type dopant to grow Si-doped β-Ga2O3 films on (100) β-Ga2O3 substrates by metal-organic chemical vapor deposition (MOCVD). The electron concentrations of the Si-doped β-Ga2O3 films obtained through experiments can be stably controlled in the range of 6.5 × 1016 cm−3 to 2.6 × 1019 cm−3, and the ionization energy of Si donors is about 30 meV, as determined by analysis and calculation. The full width at half maxima of the rocking curves of the (400) crystal plane of all doped films was less than 500 arcsec, thus showing high crystal quality, while the increase of the doping concentration increased the defect density in the β-Ga2O3 films, which had an adverse effect on the crystal quality and surface morphology of the films. Compared with heteroepitaxial Si-doped β-Ga2O3 films, homoepitaxial Si-doped β-Ga2O3 films exhibited higher quality, lower defect density, and more stable electron concentration, which make them more conductive for preparing Ga2O3-based power devices.

Highlights

  • Ga2O3 is an ultra-wide band gap semiconductor material

  • Obtaining a stable carrier concentration of β-Ga2O3 films is the key step in Ga2O3-based device fabrication [12]

  • According to an earlier report [13], the stability of electrical properties of β-Ga2O3 films is greatly affected by intrinsic defects, which is detrimental to the performance of Ga2O3 devices

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Summary

Introduction

As the most stable phase of Ga2O3, β-Ga2O3 has become one of the most promising semiconductor materials for power devices due to its band gap of 4.9 eV, its breakdown electric field of 8 MV/cm, and its Barriga figure of merit of 3444 [1]. According to an earlier report [13], the stability of electrical properties of β-Ga2O3 films is greatly affected by intrinsic defects, which is detrimental to the performance of Ga2O3 devices. This problem has not been solved yet at present. The films with different Si-doping concentrations are measured and analyzed

Materials
Experiment
Characterization
Crystal Structure Analysis
PL Characteristics Analysis
Electron Concentration Analysis
Conclusions
Full Text
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