Stabilization of heavy metals in municipal solid waste incineration fly ash via hydrothermal treatment with coal fly ash

Abstract

The environmental risk of heavy metals in hazardous municipal solid waste incineration fly ash (FA) is one of the most important concerns for its safely treating and disposing. This study investigated the stabilization behavior of heavy metals in FA using coal fly ash (CFA) as an additive via hydrothermal treatment. The effects of water washing pre-treatment and FA/CFA ratio on leaching behavior, speciation evolution, and risk assessment of heavy metals were studied. The results showed that 96.6–98.0 % of Cl can be effectively removed by water washing pre-treatment and hydrothermal treatment. Most heavy metals (Cr, Cu, Ni, Pb and Zn) (>91.5 %) were stabilized in the hydrothermal product, rather than transferred to liquid phase. Tobermorite can be synthesized by adjusting Ca/Si ratio with the addition of CFA. The heavy metals were transferred into more stable residue fractions with increasing CFA addition, which resulted in the significant reduction of leaching concentrations and risk assessment code (RAC) of heavy metals. Among, the product with 30% CFA exhibited the most superior performance with the lowest leaching concentrations of heavy metals and RAC was at no risk level (<1). In addition, the economic performance of hydrothermal treatment exhibited a potential advantage by comparing with FA-to-cement, FA-to-glass slags and FA-to-chelating agent & cement solidification/stabilization. Therefore, the hydrothermal treatment coupled with water washing pre-treatment would be a promising method for the detoxification of FA, as well as synergistic treatment of FA and CFA.