Stability of rare earth oxides in a moist environment at high temperatures—Experimental and thermodynamic studies. Part I: The way to assess thermodynamic parameters from volatilisation rates

Abstract

A methodology based on a weight loss measurement was used to quantify the volatility of yttria in high temperature water vapor. This method was first assessed on silica. Sintered materials with a shape of pellets were exposed at temperatures between 1000 and 1400 °C in air with 50 kPa of water at atmospheric pressure, under a flowing gas velocity of 5 cm s −1. Besides the volatilisation rate, the nature of the volatile gaseous species was determined using a kinetic study. Knowing the nature of flows in the furnace, partial pressures of yttrium (oxy-)hydroxide in equilibrium over Y 2O 3 were calculated, and used to assess the enthalpies of formation of YO(OH) and Y(OH) 3.