Stability of Nano-ZnO in simulated landfill leachate containing heavy metal ions.

Abstract

As the presence of nanosized zinc oxide particles (nano-ZnO) in landfill leachate increases, their interaction with coexisting heavy metal ions (HMs) also increases. The interface interaction between nano-ZnO and HMs will influence nano-ZnO stability and therefore affect its bioavailability and environmental impact. In the present study, we investigated the effects of Cu(II), Cr(III), and Cr(VI) ions on the aggregation, sedimentation, and dissolution of nano-ZnO using batch experiments with a view to better understanding their co-effect on the environment. Dynamic light scattering and UV-Vis spectroscopy results show enhanced aggregation of nano-ZnO in the presence of Cr(VI) ions under fresh landfill leachate conditions, in addition to distinct sedimentation of nano-ZnO in the presence of Cr(III) ions in both fresh and aged landfill leachate. In fresh leachate, Cu(II) ions improved the concentration of dissolved Zn from nano-ZnO. However, the effects of Cu(II), Cr(III), and Cr(VI) ions on the aggregation and dissolution of nano-ZnO were markedly reduced in aged landfill leachate. Both acetic and humic acids in landfill leachate significantly affected the stability of nano-ZnO in the presence of HMs. According to the ATR-FTIR results, Cr(III) ions reacted with hydroxyl groups on nano-ZnO to form ZnO-O bonds, which induced chains of nano-ZnO and Cr(III) complexes, and hence the increased of nano-ZnO aggregates. ATR-FTIR shows merely electrostatic adsorption effects between nano-ZnO and Cu(II) or Cr(VI) ions. In brief, the mode of interactions between HMs and nano-ZnO influenced the stability via adsorption and binding effects. The results of the present research provide insight into the potential effects of nano-ZnO on the environment in the presence of HMs in landfill leachate.