Stability of {111}Pd/{0002}ZnO polar interface formed by internal oxidation of Pd-Zn alloys.

Abstract

We investigated the stability of Pd/ZnO polar interfaces formed by internal oxidation of Pd-Zn alloys by using high-resolution transmission electron microscopy, electron energy-loss spectroscopy and convergent-beam electron diffraction. At 1273 K, a [Formula: see text] polar interface defaceted and transformed into a curved interface, while another (111)Pd/(0002)ZnO polar interface retained its flatness. The [Formula: see text] polar interface lost some stability over non-polar interfaces at 1273 K, while the (111)Pd/(0002)ZnO polar interface remained stable.