Abstract
In order to interpret the transport properties of aqueous cadmium iodide, the concentrations of free ions and complexes (CdI2–nn; n= 1, 2, 3, 4) were required. For this method the method of Reilly and Stokes was used. Potentiometric data of Bates and Bates and Vosburgh were used and overall stability constants β1, 2.66 × 102; β2, 1.42 × 103; β3, 1.11 × 105 and β4, 7.71 × 105 were obtained. The concentrations of individual complexes were then calculated for cadmium iodide solutions in the concentration range 0.001–0.50 mol dm–3.
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More From: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
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