Abstract

The regularity of the bilayer structure was compared between dipalmitoylphosphatidic acid (DPPA) Langmuir-Blodgett (LB) films and “oriented multilayers” of DPPA, using X-ray diffraction and electron spectroscopy for chemical analysis (ESCA). The angular variation of the (001) Bragg spot due to the irregularity of the lamellar repeat was remarkable in the system of oriented multilayers. In contrast, the spot of DPPA LB films exhibited only a slight angular variation, suggesting a regular structure of this film. The take-off angle dependence of the phosphorus:carbon ratio obtained by ESCA indicates that the regular layered structure in DPPA LB film is maintained after 49 layers are deposited.

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