Abstract
Stabilization of M+ Ions (M = In, Tl) by Dibenzyldichlorogallate MCl reacts with (PhCH2)2GaCl to give M[(PhCH2)2GaCl2] [M = In (1), Tl (2)]. 1 and 2 were characterized by NMR, IR and MS techniques. In addition, an X-ray structure determination of 1 was performed. According to this, 1 consists of four-membered In2Cl2 rings connected by weak In…Cl contacts (344 pm) along [010] to a coordination polymer. The In+ ion is coordinated by four In–Cl and two In-aryl interactions.
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