SrCo 0.9Sc 0.1O 3− δ perovskite hollow fibre membranes for air separation at intermediate temperatures

Abstract

SrCo 0.9Sc 0.1O 3 (SCSc) perovskite powders with sub-micron particle size were synthesized by a modified Pechini method combined with a post-treatment of sintering and ball-milling. From the prepared powders, the SCSc hollow fibre membranes with asymmetric structure and gas-tight property were fabricated by spinning a polymer solution containing 58.4 wt% SCSc followed by sintering at 1200 °C for 5 h. The oxygen permeation properties of the obtained SCSc fibres were measured under air/He gradients at 500–800 °C. This showed the oxygen flux of 1 mL cm −2 min −1 at 750 °C and 4.41 mL cm −2 min −1 at 900 °C. Modeling analysis reveals that the oxygen permeation process is predominated by oxygen surface exchange kinetics with an activation energy of 95.0 kJ mol −1. The SCSc membranes showed excellent oxygen permeation performance while exhibiting high structural and permeating stability at intermediate temperatures (500–800 °C).