Abstract

The investigation of dynamic contact angle between distilled water droplet and superhydrophobic surface was conducted experimentally. To obtain the values of contact angle during spreading, shadow method was implemented. We used Schlieren method to control the droplet symmetry. The droplet was formed on the surface by syringe pump using nontraditional bottom-up methodology. The drop growth rate was varied by the syringe pump from 0.005 ml/s to 0.32 ml/s. DCA versus drop volume was obtained for different values of the drop growth rate. Some features of spreading on superhydrophobic surface were pointed out. Interestingly, that the dynamic contact angle increases during all stages previously selected for copper substrates (1 – droplet formation; 2 – spreading; 3 – formation of the equilibrium contact angle). However, at the droplet growth rate 0.005ml/s we found decrease in the contact angle. The droplet was found to take a shape close to a spherical cap in the range of the drop growth rate 0.005 ml/s – 0.16 ml/s. At higher rates (0.32 ml/s and higher) liquid splashing was observed.

Highlights

  • Spreading of liquid droplet on a solid substrate is a general process in technology and nature

  • A surface is superhydrophobic if the contact angle (CA) of water is larger than 150° and water droplets readily slide off the surface if the surface is tilted slightly [6]

  • The process of water droplet and solid substrate contacting is characterized by two main parameters: dynamic contact angle (DCA) and three-phase contact line speed

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Summary

Introduction

Spreading of liquid droplet on a solid substrate is a general process in technology and nature. Despite much research of interface in “solid-liquid-gas” system over many years, the precise nature of three phase contact line at the dynamic interaction of a droplet with a solid surface remains only partially understood. The process of water droplet and solid substrate contacting is characterized by two main parameters: dynamic contact angle (DCA) and three-phase contact line speed.

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