Abstract

Biomass fast pyrolysis liquid (or bio-oil) is a cellulose based alternative fuel with the potential to displace fossil fuels in stationary heat and power applications. To better understand the combustion behavior and emissions of bio-oil, a 10 kW spray burner was designed and constructed. The effect of swirl, atomization quality, ignition source energy, air/fuel preheat, and equivalence ratio on the stability and emissions of bio-oil spray flames was investigated. A blend of 80% pyrolysis liquid and 20% ethanol by volume was used during the tests. Since the fuel is not fully distillable, it is important to have good atomization, thorough mixing, and increased recirculation to promote the burnout of nonvolatile material and decrease CO and hydrocarbon emissions. Air and fuel preheat are also important for reducing these emissions, although subsequent fuel boiling within the nozzle should be avoided in order to maintain flame stability. The amount of total primary air and atomizing air that can be used to improve turbulence, mixing, droplet burnout, and overall combustion quality is limited by the low volatility and tighter lean blow-out limit associated with bio-oil. The NOx produced in these flames is dominated by the conversion of fuel bound nitrogen. In order to reduce the NOx emissions without refining the fuel, the use of staged combustion is recommended.

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