Abstract

The competition between Dies-Alder cycloaddition and spontaneous concurrent polymerization was investigated in the reactions of 1-phenyl-1,3-butadiene (1) and 1-p-anisyl-1,3-butadiene (2) with electrophilic olefins. The reactions of 1 and 2 with electrophilic olefin trisubstituted with cyano and/or carbomethoxy groups have only concerted [4+2] cycloaddition products

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